MATERIAL SAFETY DATA SHEET - MSDS - PDF Free Download (2023)

MATERIAL SAFETY DATA SHEET - FISPQ

RISK COMMUNICATION PROGRAM REQUIREMENTS* 1. Written Risk Communication Program 2. Material Safety Data Sheets (MSDS) (Kepmenaker 187/1999: Control of Chemicals in the Workplace) 3. Package label: Permen LH No. 3/2008, NFPA 704, DOT ERG 4. Chemical Inventory 5. Training 6. Record Keeping/Record Keeping

* Norma OSHA 29 CFR 1910.1200

Material Safety Data Sheet (MSDS)  Purpose: The Material Safety Data Sheet (hereinafter referred to as MSDS) is to ensure that chemical and physical hazards existing in the workplace and how to deal with them are addressed. Communicate well with employees and workers so that employees and workers can safely work with the material. 

Benefits:  Explains the characteristics of certain chemicals  Provides handling procedures  Prevents accidents caused by chemicals

 Scope: All areas of the Company's production operation, both in fixed and mobile installations. Likes: 1. 2. 3. 4.

Production Collection center Main collection station Warehouse Collection station

5. Energy plan 6. Laboratory 7. Office 8. Workshop/workshop/warehouse

9. Water treatment plan 10. Tower/service 11. Well footprint 12. Etc.

Hazardous Substance Data Sheet (MSDS): Written material about a hazardous chemical that provides information about potential hazards and safe handling of the substance used.

Material Safety Data Sheet (MSDS)  Competency Requirements:  Understand the MSDS implementation process  Understand how to inventory hazardous chemicals/materials  Know the required MSDS support facilities  Understand the hazards of hazardous chemicals and materials, effects on health and necessary preventive measures measures  Understand the consequences of non-compliance with the course of the process  Be able to carry out assessments, analyzes and improvements based on recommendations.  Understand the MSDS standard  Be able to review MSDS  MSDS is generally divided into 7 sections that cover the following types of information:  Identification  Hazardous Items  Fire and Explosion Hazard Data  Physical Data  Health Risk Data  Special Protection Information  Spill or Leak Management Procedures and Special Precautions

Action

Material Safety Data Sheet (MSDS)  Equipment:  SBU Hazardous Chemicals Inventory Sheet _________________________ UNIT LOCATION/LOCATION AREA FIELD

_________________________ _________________________ _________________________ _________________________

Substance name Material name

Dangerous Material Data Sheet from Chemical Inventory Records

WORKPLACE WORKPLACE __________________________

Manufacturer name Nama Pabrik

Limit: 25 characters Limit: 25 characters

PHY FRM-Fitness

APPLICATION - Application/Use

SP = Powder LQ = Liquid Flour Liquid SG = Granule LG = Liquid Gas Liquid Gas Granules SF = Flakes LS = Soft Mix Flakes SO = Other Solids GS = Gas Other Solid Materials.

Chemical Inventory MSDS Record Sheet

M S D S

S/N Sim/Tdk

R= Raw material C = Catalyst/Raw material Catalyst W = Waste (for disposal) I = Intermediate waste (Disposal) Intermediate material S = Supply of consumables A = Additive Consumed material Additive O = Other/Other P = Product/ Products or by -products Products

Issue date Issue date

Start date Start date

PHY end date The FRM date is no longer used

dd/mm/aa hr/bln/thn

QUANTITY - Amount used/month Jumlah terpakai/bulan A = <10 lb/pon or < 1 gallon B = 10-100 lb/pon or 1-10 gallon C = 100-1000 lb/pon or 10-100 gallon D => 1000 lbs/pon or >100 gallons

APP

C T Y

P K G USG

function of fungi

Use the codes below Use the codes below

Limit: 25 characters Limit: 25 characters

PKG - Pack B = Bulk / Larger Volume (Tube, Railcar / Tank Truck, Tote Bin / Container, etc.) L = Big Pack / Big Pack, Drum, Bag / Sack > 10 lbs / lbs Bucket / Buckets 5 gallons, etc.) S = Small Packages (Bottles/Bottles, Cans/Cans, Boxes/Two, etc.)

USG - Use OP = Operation Operation MN = Maintenance Maintenance LA = Laboratory/Laboratory. Locally defined additional codes

Material Safety Data Sheet (MSDS)  Equipment:  MSDS  All chemicals contained in the inventory sheet must be accompanied by an MSDS  The MSDS must be at the work site (close to the place of use and storage)

Material Safety Data Sheet (MSDS)  Equipment:  Labels  Facility supervisors must label each chemical/material container.  All drums and containers of hazardous materials must be labeled and prominently displayed. There are three (3) tagging systems that can be used by each facility: • NFPA (National Fire Protection Agency) • HMIS (Hazardous Materials Information System) • Placards – used for shipping purposes only.

norte

POISON

FLAMMABLE

OXIDIZING

Poster

PACKAGING LABELS

VERY POINT

NFPA 704

Regulation of the Minister for the Environment 3/2008

Material Safety Data Sheet (MSDS) FLAMMABILITY Flash point less than 73°F and boiling point less than 100°F: This substance is highly flammable, volatile or explosive, depending on its state. Great care must be taken when handling or storing these materials.

Can detonate: Substances that are readily capable of detonating or exploding at normal temperatures and pressures. Evacuate area if exposed to heat or fire.

Explosive: Substances that are readily capable of detonation or explosion by a strong initial source such as heat, shock or water. Monitoring behind blast-resistant barriers

Unstable: Violent chemical changes are possible at normal or elevated temperatures and pressures. A potentially violent or explosive reaction can occur when mixed with water. Watch from a safe distance.

Death: Even the slightest exposure to this substance can be fatal. Only specialized protective clothing should be used for these materials.

Extreme Danger: Exposure to this substance can cause serious injury. Do not expose any body surfaces to these materials. Complete protective measures must be taken.

Hazardous: Exposure to this substance would be hazardous to health. Protective measures are indicated.

Flash Point Below 200ºF: Moderately hot conditions can ignite this substance. Cautious handling procedures must be employed.

Mild Hazard: Exposure to this substance may cause irritation or minor injury. The protective measures are indicated

Flash point greater than 200°F: This substance must be preheated to ignite. Most solid fuels would be in this category.

Normally Stable: Substances that can become unstable at elevated temperatures and pressures or when mixed with water. Approach carefully.

No Hazard: Exposure to this substance does not pose any significant health risk.

Will Not Burn: substances that do not burn.

Stable: Substances that will remain stable when exposed to heat, pressure or water.

SPECIFIC HEALTH RISK >

OXI ACID ALK COR W

Flash Point Below 100°F: Flammable, volatile, or explosive under most normal temperature conditions. Take great care when storing or handling these materials.

-------

Oxidant Acid Alkaline Corrosive use No radiation hazard from water

REACTIVITY

 Safety shower/eyewash  Safety shower and eyewash must be provided if there is potential for exposure to hazardous chemicals (corrosive, can cause severe irritation, permanent skin damage, or is toxic if inhaled).  This unit must be located between 3 and 15 meters from potential hazards.

Material Safety Data Sheet (MSDS)  Equipment:  Specific PPE  Asset owners must provide specific PPE for handling chemicals, such as chemical protective clothing, goggles, face shields, gloves and special footwear.  Hazardous Chemical Area Identification  The hazardous chemical area should be identified with "yellow lines".  Warning and Information Signs  Must be posted to alert employees to hazard, required requirements and chemical information.  Documentation  Hazardous materials inventory list  Accident Investigation Reports related to incidents resulting from non-compliance with the use of MSDS.  PEKA report  Violation of MSDS requirements (NearMiss)  Disciplinary action  MSDS related inspection results  Training records

6. Material Safety Data Sheet (MSDS) - Implementation of the Person Responsible for Facility Operations (FO)

Start

new things

existing materials

Create a purchase request

Acquisition (SCM Function)

HSE HES HSE

Issue of purchase orders

Inventory Conducting a Hazardous Materials Inventory

Ask Mintake supplier to prepare MSDS

Use MSDS Inventory Sheets Facilities must designate a person responsible for maintaining and updating inventory

Submit MSDS for FO and HES HSE facility

MSDS MemeriksaMSDS

Complete and document MSDS training

Including training, installation and labeling.

Training and Communication MSDS MSDS

Stop

Material Safety Data Sheet (MSDS)  Kasus Study:

Discuss with each group:  Name the chemicals found in each facility/workplace.  Estimate the actual volume  Indicate the potential hazard that exists from the chemical

MSDS

- MATERIAL OF THE MATERIAL SAFETY DATA SHEET

1. Product Information Name: VARSOL-1 SOLVENT Company Name: EXXON CO, Tel Emer #: 713-656-3424 2. MSDS Manufacture MSDS Manufacture Date: 12APR95 Evaluation Date: 13JUN96 MSDS Manufacturer Name: MARKETING TECHNICAL SER manufacturing company: EXXON COMPANY ,

3. Raw Materials Raw Materials: STODDARD SOLVENT Base Material Order No.: 01 Percentage: 100 CAS No.: 8052-41-3 OSHA PEL: 500 PPM ACGIH TLV: 100 PPM

4. Physical Properties Appearance and Odor: Clear water – a white liquid with a mineral scent. Boiling Point: 315F,157C Melting Point: <0F,<-18C Vapor Pressure (MM Hg/70 F):[email protected]Vapor Density (air = 1): 3.5 Specific Gravity: 0.80 Water Solubility: Negligible Percentage Volatile by Volume: 100 pH: NEUTRAL 5. Fire and Explosion Data Flash Point: 104 F, 40 C Limit lower explosion: 2.1% Upper explosion limit: 13.3% Flash point is the lowest temperature at which a liquid produces enough vapor to ignite from an ignition source. The lower the flash point, the greater the risk of fire.

MSDS

- MATERIAL OF THE MATERIAL SAFETY DATA SHEET

5. Fire and Explosive Data, continued Toxic Fire Media: Foam, H2O spray (fog), dry chemical, CO2 Pros. Special Fire Fighting: Flush burning containers with water to keep cool Unusual Fire and Explosion Hazards: Liquid is volatile; can be installed in low areas

7. Toxicological Information, continued Symptoms/Signs of Overexposure: High vap concentration (>1000 ppm), irritation to eyes, respiratory tract, headache, dizziness, anaesthesia, drowsiness, other CNS effects including death. Carcinogenicity - OSHA: NO

6. Product reactivity Hazardous decomposition products : vapour, fumes, CO, sulfur oxides, aldehydes Hazardous polymerization : No

LC50 (Lethal Concentration 50) is the amount of a substance in the air that, when administered by inhalation over a period of time, is believed to cause the death of 50 percent of the experimental animal population.

7. LD50-LC50 compound toxicological information: ORAL LD50 (Rabbit) >3.16G/KG body weight Route of Entry - Inhalation: YES Route of Entry - Skin: YES Route of Entry - Gastrointestinal: NO

LD50 (lethal dose50) is the amount of a substance which, when administered by a specified route of administration (eg, oral or dermal) for a specified period of time, is believed to cause 50% of deaths in the experimental animal population

MSDS

- MATERIAL OF THE MATERIAL SAFETY DATA SHEET

8. Respiratory Protection Precautions: Not specified by the manufacturer Ventilation: Use only normal ventilation to avoid exceeding recommended exposure limits. Eye protection: gogg, face shields. Other Protective Equipment: Chemical resistant apron/other clothing if needed. Storage: Keep container tightly closed when not in use. Keep away from heat/sparks/fire/concentrated acid. Grind effectively. NFPA: Use of appropriate equipment. NFPA-70.

8. Precautions (continued) Spill: Eliminate ignition source, keep personnel away. Save what's left. Cover with sand/earth/other absorbent. Minimize steam inhalation/skin contact. Ventilation of confined spaces. Open the window/door wide. Prevent the entry of watercourses, gutters making embankments. Comply with government regulations. 9. First Aid Measures Emergency Procedures: EYES: Flush with water for 15 minutes until irritation subsides. If so, call paramedics. SKIN: Remove contaminated clothing. Clean the skin with water/soap/water.